🔮 Rare Earth Elements (REEs)
Definition · 17 REEs · Light vs Heavy · Properties · Applications · China Monopoly · India's Position · US-China Trade Tensions 2025 · UPSC PYQ 2025 · MCQs
Rare Earth Elements in the Periodic Table. Purple boxes (Group 3): Scandium (Sc-21, Period 4) and Yttrium (Y-39, Period 5) — included as REEs due to similar chemical/physical properties and co-occurrence in same ore deposits. Yellow-green boxes (bottom row, Period 6 Lanthanide series): Cerium (Ce-58) through Lutetium (Lu-71) — the 14 lanthanides. Note: Lanthanum (La-57) shown in Period 6, Group 3. Total REEs = 17 (Sc + Y + 15 lanthanides). They are separated to the bottom of the periodic table for space reasons — they are actually part of Period 6 and 7. (Uploaded image — Legacy IAS)
• High density, high melting point, high conductivity, high thermal conductance
• Shiny silvery-white metals (tarnish in air)
• Highly reactive — react with water, oxygen
• Strong magnetic properties (especially Nd, Dy, Sm)
• Phosphorescent properties (Eu, Y, Tb) — emit light when excited
• Most abundant REE: Cerium (Ce) — approximately same abundance as copper
• Least abundant: Promethium (Pm) — entirely radioactive (no stable isotopes)
La, Ce, Pr, Nd, Pm, Sm, Eu
More abundant. Nd is most critical LREE.
Heavy REEs (HREEs): Atomic numbers 64–71 (+ Sc, Y)
Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu
Less abundant but MORE CRITICAL for high-tech uses. Dy and Y especially critical for clean energy.
India context: India has mainly Light REEs (in monazite). Heavy REEs are NOT available in extractable quantities in India — a key strategic vulnerability.
Critical vs Uncritical: REEs in high demand + low supply = Critical (Nd, Dy, Y, Eu, Tb, Er, Sc). REEs with sufficient supply = Uncritical or Excessive.
All 17 Rare Earth Elements — Complete Reference Table. Sorted by discovery year (1788–1947). Key observations: (1) Most were discovered in the 19th century (1803–1886). (2) Promethium (Pm-61) discovered last (1947) — it is entirely synthetic/radioactive, no stable isotope. (3) Critical REEs (high demand, low supply): Yttrium, Erbium, Terbium, Scandium, Neodymium, Dysprosium, Europium. (4) Neodymium (Nd-60) and Dysprosium (Dy-66) are the most critical for EV motors and wind turbines. (5) Scandium and Yttrium are classified as Heavy REEs despite their relatively low atomic numbers. (Source: The Print; Uploaded image — Legacy IAS)
"Lazy Cows Produce No Particular Smell Even Given The Density Help Entering The Yard Laughing"
Or remember atomic numbers: La(57) → Lu(71) — 15 elements. Light REEs: La to Eu (57–63). Heavy REEs: Gd to Lu (64–71).
| Symbol | Element | Z | Type | Criticality | Key Use |
|---|---|---|---|---|---|
| La | Lanthanum | 57 | Light | Uncritical | Camera lenses (up to 50%), hybrid car batteries, petroleum refining catalyst |
| Ce | Cerium | 58 | Light | Excessive | Most abundant REE. Catalytic converters, water purifiers, glass polishing, steel making |
| Pr | Praseodymium | 59 | Light | Uncritical | Permanent magnets (NdFeB with Nd), aircraft engines, high-strength alloys. India extracts this. |
| Nd | Neodymium | 60 | Light | Critical | Nd-Fe-B permanent magnets (strongest) — EV motors, wind turbines, hard disks, smartphones. India extracts this. |
| Pm | Promethium | 61 | Light | Unique | Entirely radioactive (no stable isotope). Discovered 1947. Beta radiation source, nuclear batteries. |
| Sm | Samarium | 62 | Light | Uncritical | High-temperature magnets (Sm-Co), cancer treatment (Sm-153 for bone cancer) |
| Eu | Europium | 63 | Light/Heavy* | Critical | Phosphors for flat TV screens, monitors, fluorescent lamps. Red/blue colour in displays. |
| Gd | Gadolinium | 64 | Heavy | Uncritical | MRI contrast agent, nuclear reactor control rods, cancer treatment |
| Tb | Terbium | 65 | Heavy | Critical | Phosphors (green colour in flat screens), solid-state devices, fuel cells |
| Dy | Dysprosium | 66 | Heavy | Critical | Additive to Nd magnets for high-temperature operation (EV motors need this). Most critical HREE for clean energy. |
| Ho | Holmium | 67 | Heavy | Excessive | Highest magnetic strength of any element. Laser surgery, MRI |
| Er | Erbium | 68 | Heavy | Critical | Fibre optic cables, laser repeaters, nuclear technology |
| Tm | Thulium | 69 | Heavy | Excessive | Portable X-ray machines, lasers, high-temperature superconductors |
| Yb | Ytterbium | 70 | Heavy | Excessive | Atomic clocks, fibre-optic amplifiers, cancer research |
| Lu | Lutetium | 71 | Heavy | Excessive | PET scanner detectors, cancer treatment (Lu-177), LED technology |
| Sc | Scandium | 21 | Heavy* | Critical | Al-Sc alloys (aerospace), solid oxide fuel cells, sports equipment (bike frames) |
| Y | Yttrium | 39 | Heavy* | Critical | Phosphors in LED/flat screens, high-temperature superconductors, cancer treatment (Y-90) |
* Sc and Y are classified with Heavy REEs due to similar chemical properties despite lower atomic numbers. Eu at boundary of light/heavy.
Used in: EV motors, wind turbine generators, hard disk drives, headphones, MRI machines, anti-lock brakes, power steering, electric windows, audio speakers, digital cameras, CD-ROMs.
Dysprosium (Dy) added to Nd magnets for high-temperature resistance in EV motors. Samarium-Cobalt (Sm-Co) magnets for extreme conditions.
Lanthanum (La): Makes up 50% of digital camera lenses (including cell phone cameras).
Erbium (Er): Fibre optic cables and laser repeaters.
All smartphones contain ~16 different REEs.
• Wind turbines: Nd-Fe-B magnets in generators
• Electric vehicles: Nd (motors) + Dy (high-temp Nd magnets) + La (batteries)
• Nickel-metal hydride batteries: La-based alloys as anodes
• Cerium catalysts: Automotive catalytic converters
• Solar panels: REEs in thin-film solar cells
A single EV motor requires ~1 kg of Nd. A wind turbine requires ~200 kg of REEs.
• Precision-guided missiles: Sm-Co magnets, Nd magnets in guidance systems
• Radar systems: REEs in signal processing components
• Jet engines: REE alloys for high-temp turbine blades
• Sonar: Terfenol-D (Dy-Fe alloy) — magnetostrictive material
• Satellite communications: REEs in transmission equipment
• Night vision: REE-doped glass for thermal imaging
• Each F-35 fighter jet uses ~417 kg of REEs.
• PET scanners: Lu-177, Y-90 radioisotopes
• Cancer treatment: Sm-153 (bone cancer pain relief), Y-90 (liver cancer), Lu-177 (targeted therapy)
• Laser scalpels: Er lasers in surgery
• Antiseptic dressings: Ce-based non-irritating dressings
• Portable X-ray: Tm-based sources
• Glass industry: Largest consumer of REE raw materials — polishing, colouring, optical properties
• Water purification: Ce's affinity for phosphorus — removes phosphorus from wastewater
• Steel making: Ce+La+Nd+Pr (as mischmetal) remove impurities, produce special alloys
• Agriculture: REE fertilisers used in China for crop yield improvement
Global Rare Earth Element Reserves (REO basis). World total: 132 million tonnes of REE Oxide (REO). China leads with 44 million tonnes (33.33%). Brazil and Vietnam tied at 22 million tonnes each (16.67%). Russia: 18 million tonnes (13.64%). India: 6.9 million tonnes (5.23%) — 5th largest globally. Australia: 3.4 million tonnes. Note: Despite having only 33% of reserves, China controls 60–70% of mining and ~90% of global processing — due to decades of infrastructure investment and low-cost processing. REO = Rare Earth Element Oxide. (Uploaded image — Legacy IAS)
Mining: 60–70% of global REE mining output
Processing/Refining: ~90% of global refined REE output
Magnets: Dominates REE magnet supply chain
Since the 1990s, China has provided 90–95% of world's REEs by:
• Massive subsidies to REE industry
• Low environmental standards (accepting toxic waste)
• Deliberately low prices to drive out foreign competitors
• Export quotas and restrictions as geopolitical leverage
Recent: China imposed export curbs on 12 rare earth elements (2025) — triggering US-China REE trade tensions. Global REE prices surged 35–40%.
Environmental damage from REE mining:
• For every 1 tonne of REE, ~2,000 tonnes of toxic waste produced
• China produces tens of millions of tonnes of radioactive wastewater annually
• Soil and water contamination near mines
• REE ores often contain radioactive thorium and uranium → health risks for miners
Health risks: Radioactive thorium and uranium laced in REE ores → detrimental health effects during extraction
This creates the "Rare Earth Dilemma" — we need REEs to save the planet from climate change, but extracting them damages the environment.
Coastal beach placer deposits (primary):
• Andhra Pradesh
• Odisha
• Kerala (especially rich — Aluva processing plant)
• Tamil Nadu
• Maharashtra
• Gujarat (recent: Carbonatite deposit found)
Inland placer deposits:
• Jharkhand
• West Bengal
• Tamil Nadu
Processing plants: IREL plants at Ganjam (Odisha) and Aluva (Kerala)
Important: Monazite also contains radioactive thorium and uranium → classified as atomic mineral → mining restricted to government entities (IREL, KMML) under Atomic Minerals Directorate.
• Can extract Light REEs from monazite
• Nd and Pr extracted at 99.9% purity
• IREL (Indian Rare Earths Ltd) — established mining and processing
• RE & Titanium Theme Park (IREL-BARC collaboration)
• Carbonatite deposit found in Gujarat (new source)
• Joint venture: Toyotsu Rare Earths India Ltd (Toyota Tsusho + IREL, Visakhapatnam)
• No industrial-scale alloy and magnet production
• Atomic mineral tag restricts private sector participation
• 2016 ban on beach sand mining (thorium conservation) → supply bottleneck
• Disjointed R&D — academia-industry gap
• PSUs prioritise profitable minerals over REEs
• 90% import dependence on China
• India holds ~9 million tonnes of REE reserves (USGS, 2024)
• Critical Minerals Mission (2023): India's push for self-reliance in REEs and other critical minerals
• Scope to expand IREL (Indian Rare Earths Ltd)
• India's position in Quad Critical Minerals Partnership (2022)
• Indo-Pacific Economic Framework (IPEF): diversifying global REE supply chains
| Initiative / Framework | Description | India's Role |
|---|---|---|
| Critical Minerals Mission (2023) | India's dedicated mission for self-reliance in critical minerals including REEs, lithium, cobalt | Lead agency: Ministry of Mines. IREL expansion. New NALCO/HCL ventures |
| Quad Critical Minerals Partnership (2022) | USA, Japan, Australia, India partnership to secure critical mineral supply chains | India contributes REE deposits; imports processing technology from partners |
| Minerals Security Partnership (MSP) | US-led grouping of 14 countries to develop secure supply chains for critical minerals | India is a member; diversifying REE sources away from China |
| Toyotsu Rare Earths India Ltd | Joint venture: Toyota Tsusho Corporation (Japan) + IREL, Visakhapatnam | Refining rare earths through Japan's technology and India's monazite access |
| RE & Titanium Theme Park | IREL + BARC collaboration for REE processing technology commercialisation | Technology transfer from BARC's nuclear expertise to REE processing |
| Indo-Pacific Economic Framework (IPEF) | US-led economic framework including India, Japan, Australia for supply chain resilience | Supply chain pillar: REEs, semiconductors, pharma diversification |
Statement I: Some rare earth elements are used in the manufacture of flat television screens and computer monitors.
Statement II: Some rare earth elements have phosphorescent properties.
Which one of the following is correct in respect of the above statements?
- a) Both Statement I and Statement II are correct and Statement II explains Statement I ✓
- b) Both Statement I and Statement II are correct but Statement II does not explain Statement I
- c) Statement I is correct but Statement II is not correct
- d) Statement I is not correct but Statement II is correct
Statement II CORRECT: Phosphorescence is a form of photoluminescence — the property of emitting light after absorbing radiation. Europium (Eu), Yttrium (Y), and Terbium (Tb) have this phosphorescent property. Eu provides red and blue colour; Tb provides green colour in display phosphors.
Why Statement II EXPLAINS Statement I: It is PRECISELY BECAUSE some REEs have phosphorescent properties that they are used in flat TV screens and computer monitors. The phosphorescent property → emission of specific colours when excited → used in displays. The causal mechanism flows directly from S-II to S-I. This is a "Statement I and II correct and II explains I" pattern — answer is (a).
- (a) Dysprosium is added because it significantly increases the electrical conductivity of Nd-Fe-B magnets, reducing energy losses in the EV motor circuit and improving overall motor efficiency by approximately 40%
- (b) Dysprosium is added because it is far more abundant than neodymium and therefore cheaper, allowing manufacturers to reduce the neodymium content in EV magnets while maintaining the same magnetic strength at lower cost
- (c) Dysprosium is added because EV motors operate at high temperatures (up to 200°C during peak load), and pure Nd-Fe-B magnets lose their magnetic properties above about 80°C; Dysprosium significantly raises this temperature limit, allowing the magnets to maintain performance under the extreme thermal conditions of EV motor operation
- (d) Dysprosium is added to Nd-Fe-B magnets specifically for EV applications to reduce the weight of the motor — Dy atoms are much lighter than Nd atoms and substituting some Nd with Dy reduces the magnet's mass by approximately 30%, extending the EV's range
- (a) India's REE reserves are classified as "strategic reserves" and the government has deliberately chosen not to mine them, keeping them as a diplomatic bargaining tool with other nations in rare earth negotiations
- (b) Multiple structural barriers prevent India from converting its REE deposits into processed compounds: monazite's radioactive thorium content classifies it as an atomic mineral limiting mining to government entities; India lacks industrial-scale refining infrastructure for heavy REEs; the 2016 beach sand mining ban restricted access to monazite; and the high environmental costs and dispersed deposits make domestic extraction less economically competitive than Chinese imports
- (c) India's REE reserves are entirely of the heavy REE type (like dysprosium and terbium) which require fundamentally different processing technology than light REEs; since no country has yet developed cost-effective heavy REE extraction, India's reserves remain untapped pending international technology development
- (d) The Indian government has signed exclusivity agreements with China for all REE processing, preventing India from developing domestic REE processing capacity until these agreements expire in 2030
- (a) The dilemma is that rare earth elements are simultaneously critical for both military and civilian use — making it impossible for exporting countries to determine whether imports will be used for peaceful purposes, creating a dual-use technology control challenge
- (b) The dilemma refers to the economic contradiction where increasing REE production to meet clean energy demand drives down prices, making REE mining unprofitable and eventually causing production to collapse before clean energy goals can be met
- (c) The dilemma is that rare earth elements are named "rare" but are actually abundant, creating public confusion about supply security and causing governments to over-invest in stockpiling when supply is actually adequate for centuries of clean energy needs
- (d) The Rare Earth Dilemma is that REEs are essential components of clean energy technologies (EVs, wind turbines) that are supposed to reduce environmental damage — yet the process of extracting REEs causes severe environmental harm including toxic waste (2,000 tonnes per tonne of REE), radioactive contamination from co-occurring thorium/uranium, and massive wastewater generation — creating a paradox where addressing climate change requires activities that damage the very environment we seek to protect
| Topic | Key Facts |
|---|---|
| Definition | 17 metallic elements: 15 Lanthanides (La-57 to Lu-71) + Scandium (Sc-21) + Yttrium (Y-39). Located in Group 3 of periodic table. "Rare" = dispersed, not easily concentrated; actually moderately abundant. All share +3 oxidation state and similar ionic radii. |
| Light vs Heavy | Light REEs (LREEs): La to Eu (Z=57–63) — more abundant. Heavy REEs (HREEs): Gd to Lu (Z=64–71) + Sc + Y — less abundant, MORE CRITICAL for clean energy. Cerium = most abundant REE. Promethium (Pm) = only entirely synthetic/radioactive REE. |
| Critical REEs | Most critical: Neodymium (Nd) — EV motors, wind turbines. Dysprosium (Dy) — high-temp Nd magnets. Europium (Eu) — display phosphors (red/blue). Terbium (Tb) — display phosphors (green). Yttrium (Y) — phosphors + superconductors. Scandium (Sc) — aerospace alloys. |
| Key Applications | Nd-Fe-B permanent magnets (strongest magnets, EV/wind turbines). Phosphors (Eu/Y/Tb → flat screens, monitors). La → camera lenses (50%), petroleum refining, batteries. Ce → catalytic converters, water purifiers, glass polishing. Gd → MRI contrast. Er → fibre optics. Each EV = ~1kg Nd. Each wind turbine = ~200kg REEs. |
| Ore Sources | Monazite (phosphate — India's main source), Bastnaesite (fluorocarbonate — China/USA), Xenotime (Y-phosphate), Loparite (Russia), Ion-adsorption clays (China — heavy REEs). |
| Global Reserves | World: 132 million tonnes REO. China 37% (44M t), Brazil+Vietnam 16.67% each (22M t each), Russia 13.64% (18M t), India 5.23% (6.9M t = 5th largest). China controls 60–70% mining + 90% processing. |
| India | 5th largest reserves (13.07M tonnes; USGS: 9M tonnes). 6% of world. Mainly Light REEs in monazite beach sands (AP, Odisha, Kerala, TN, Maharashtra, Gujarat). No extractable Heavy REEs. IREL = key miner (Ganjam-Odisha, Aluva-Kerala). 90% import dependence on China. Nd+Pr extracted at 99.9% purity. Toyotsu JV (Vizag). Carbonatite deposit found in Gujarat. |
| 2025 Current Affairs | China export curbs on 12 REEs → US-China trade tensions. REE prices surged 35–40%. India imports 90% from China (2,270 tonnes FY24). Critical Minerals Mission 2023. Quad Critical Minerals Partnership 2022. Minerals Security Partnership (MSP). IPEF supply chain pillar. "Friend-shoring" to Australia, Vietnam. Japan Urban Mining Model (Nd+Dy recycling from e-waste). |
| UPSC PYQ 2025 | "Some REEs used in flat TV screens and monitors" (S-I) because "some REEs have phosphorescent properties" (S-II). Answer: (a) Both correct and S-II explains S-I. Eu/Y/Tb have phosphorescent properties → used as phosphors in displays. |
| Rare Earth Dilemma | REEs needed for green technology (EVs, wind turbines) but extraction produces 2,000 tonnes toxic waste per tonne REE; radioactive thorium/uranium health risks; China's wastewater problem. Paradox: saving environment via technologies that damage environment. |
Trap 1 — "Rare Earth Elements are actually rare in Earth's crust" → WRONG! REEs are moderately abundant in Earth's crust — they are "rare" only because they are rarely found in concentrated, economically viable deposits. Cerium (most abundant REE) has roughly the same crustal abundance as copper. The name "rare" is historical — these elements were once thought to be scarce because their concentrated mineral deposits are uncommon. UPSC 2025 PYQ context: the paradox of "rare but abundant" is core to REE policy discussions.
Trap 2 — "China has the largest REE reserves globally, followed by India" → WRONG (ranking error)! China has the largest reserves (~37% / 44 million tonnes). But Brazil and Vietnam are tied for second (16.67% each, 22 million tonnes), followed by Russia (13.64%). India is FIFTH (5.23%, 6.9 million tonnes). The common mistake is placing India second or third. Also note: China having the largest reserves (~37%) does NOT fully explain its 90% share of global processing — that dominance comes from decades of processing infrastructure investment, not just reserve size.
Trap 3 — "India has significant Heavy REE deposits that are unexploited due to policy challenges" → WRONG! India has mainly LIGHT REEs (in monazite sands). Heavy REEs (Dysprosium, Terbium, Yttrium, Erbium) are NOT available in extractable quantities in India. This is a major strategic gap because Heavy REEs are the most critical for clean energy (Dy for high-temperature EV magnets, Y for phosphors and superconductors). Even if all policy barriers were removed, India could not mine significant Heavy REEs — it needs to import or develop alternative sources.
Trap 4 — "Promethium (Pm) is the most abundant Rare Earth Element" → WRONG (should be Cerium)! Cerium (Ce) is the most abundant REE — roughly as common as copper. Promethium is actually the rarest — it has NO stable isotopes (entirely radioactive) and occurs naturally only in trace amounts from uranium decay. It was last in the list of lanthanides to be discovered (1947). Pm is the only REE that cannot be found in significant quantities in Earth's crust.
Trap 5 — "Scandium and Yttrium are classified as Light REEs because of their low atomic numbers" → WRONG! Despite having low atomic numbers (Sc=21, Y=39), Scandium and Yttrium are classified with HEAVY REEs — because they have similar chemical and physical properties to the heavy lanthanides and are found in the same ore deposits as heavy REEs. Classification is by chemical behaviour and ore association, not just by atomic number. Also: Europium (Eu-63) sits at the LREE-HREE boundary and is sometimes listed in either group depending on the classification scheme used.


