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PIB Summaries 21 June 2025

  1. India’s solar leap to produce Green Hydrogen by splitting water molecules using only solar energy


Scientific Breakthrough

  • Scientists at Centre for Nano and Soft Matter Sciences (CeNS), Bengaluru, under DST, developed a next-generation solar device.
  • The device produces green hydrogen by splitting water molecules using only solar energy, without fossil fuels or expensive rare materials.

Relevance : GS 3(Science and Technology)

What is Green Hydrogen?

  • Cleanest fuel capable of:
    • Decarbonizing heavy industries
    • Powering zero-emission vehicles
    • Storing renewable energy effectively
  • India aims to become a global leader in Green Hydrogen Mission under its clean energy transition.

Technology Highlights

  • Built using n-i-p heterojunction (n-type TiO₂, intrinsic Si, p-type NiO).
  • Silicon-based photoanode boosts:
    • Light absorption
    • Charge separation and transport
    • Minimizes recombination losses
  • Fabrication via magnetron sputtering, an industry-ready, scalable technique.

Performance & Efficiency

  • Achieved:
    • 600 mV surface photovoltage (SPV)
    • Low onset potential of ~0.11 V_RHE
    • Over 10 hours continuous operation with only 4% degradation in alkaline conditions.
  • Demonstrated at large-scale (25 cm² photoanode) — proving real-world viability.

Significance

  • Combines efficiency, scalability, and affordability — rare in current green hydrogen tech.
  • Enables direct solar-to-hydrogen conversion with earth-abundant, non-toxic materials.
  • Supports India’s goal of achieving energy self-reliance and net-zero emissions by 2070.

Research Impact & Future Scope

  • Published in Journal of Materials Chemistry A (Royal Society of Chemistry).
  • Encourages future development of solar-hydrogen systems for homes, factories, and mobility.
  • Sets a global benchmark in clean hydrogen innovation.

Photoelectrochemical (PEC) Water Splitting – CeNS Device (2025)

Pros:

  • One-step, clean conversion – no need for external electricity.
  • Scalable using abundant materials (Si, TiO₂, NiO).
  • Low operating voltage (0.11 VRHE) → efficient.
  • Demonstrated long-term stability (10+ hrs, only 4% drop).

Cons:

  • Still in R&D stage – not yet widely commercialized.
  • Efficiency lower than best electrolysis methods (as of now).
  • Sensitive to material degradation over time and conditions.

Comparison Table

MethodProsCons
Electrolysis (RE-based)Mature, modular, high purityHigh cost, two-system dependency
Biomass GasificationWaste utilization, multi-outputPartial emissions, supply chain issues
PhotobiologicalNatural, ambientVery low efficiency, not scalable
Solar Thermal SplittingNo electricity, high theoretical yieldComplex, high-temp tech
PEC (CeNS 2025)Single-step, efficient, scalableResearch stage, stability concerns

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